Generally, 0.2 wt.%, is sufficient for this purpose. Conversion of complicated chemical-related units is no longer sophisticated with the aid of UnitPot. The following examples are provided to illustrate, but not to limit, the scope of the invention described herein. A chemical formula of N-Benzylidene-p-anisidine can therefore be written as: The chemical formula of N-Benzylidene-p-anisidine shown above is based on the molecular formula indicating the numbers of each type of atom in a molecule without structural information, which is different from the empirical formula which provides the numerical proportions of atoms of each type. It can provide a standard way to encode the molecular information of 2-Benzylidene-1,3-dioxolane to facilitate the search for the compound information in databases and on the web. The chemical structure image of N-Benzylidene-p-anisidine is available in chemical structure page of N-Benzylidene-p-anisidine, which specifies the molecular geometry, i.e., the spatial arrangement of atoms in the chemical formula of N-Benzylidene-p-anisidine and the chemical bonds that hold the atoms together. The list of the other names (synonyms) of N-Benzylidene-p-anisidine including the registry numbers is given below, if available: Visit ChemTopia for further professional chemical information on the basis of a comprehensive intelligence networking platform for experts in the discipline around the globe. The process of claim 1 wherein the temperature is in the range of 150.degree. An alternative textual expression including the structural information is InChI. CC(=O)OC(c1ccccc1)OC(=O)C
Thus, each side of the chemical equation must represent the same quantity of any particular element based on the chemical formula. CopyCopied, CSID:21242158, http://www.chemspider.com/Chemical-Structure.21242158.html (accessed 09:22, Nov 12, 2020)
A chemical formula of 2-Benzylidene-1,3-dioxolane can therefore be written as: The chemical formula of 2-Benzylidene-1,3-dioxolane shown above is based on the molecular formula indicating the numbers of each type of atom in a molecule without structural information, which is different from the empirical formula which provides the numerical proportions of atoms of each type. An alternative textual expression including the structural information is InChI. 192
2. As aforestated, the process of this invention comprises reacting benzylidene diacetate in acetic anhydride in the presence of air or oxygen and an acid catalyst at elevated temperatures to yield phenyl acetate and methylene diacetate in accordance with the following reaction: ##STR1##. .degree.C. The full standard InChI of 2-Benzylidene-1,3-dioxolane is: InChI=1S/C10H10O2/c1-2-4-9(5-3-1)8-10-11-6-7-12-10/h1-5,8H,6-7H2. The acid catalyst is desirably sulfuric acid, but other like acids such as peroxymonosulfuric acid, Caro's dry reagent, or mixtures thereof, may be used instead. C., preferably 200.degree. Std. The 1 H nuclear magnetic resonance spectral parameters are reported for benzylidene diacetate in CS 2 and acetone-d 6 solutions. The contents of this page can freely be shared if cited as follows:
The full standard InChI of N-Benzylidene-p-anisidine is: InChI=1S/C14H13NO/c1-16-14-9-7-13(8-10-14)15-11-12-5-3-2-4-6-12/h2-11H,1H3/b15-11+. The law of conservation of mass dictates that the quantity of each element given in the chemical formula does not change in a chemical reaction. The N-Benzylidene-p-anisidine structure data file can be imported to most of the cheminformatics software for further analysis and visualization. A process for the production of phenyl acetate and methylene diacetate which comprises reacting benzylidene diacetate with air or oxygen at elevated temperatures and pressures in the presence of acetic anhydride and an acid catalyst. There are 13 Hydrogen atom(s), 14 Carbon atom(s), 1 Nitrogen atom(s) and 1 Oxygen atom(s). I. 3-Benzylidene camphor UNII-2F60H204CM 2F60H204CM EINECS 239-139-9 EINECS 252-857-7 1,7,7-Trimethylbicyclo(2.2.1)heptan-2-one-3-benzylidene Bicyclo(2.2.1)heptan-2-one, 1,7,7-trimethyl-3-(phenylmethylene)-15087-24-8 Thus, each side of the chemical equation must represent the same quantity of any particular element based on the chemical formula. The molecular chemical formulas lack structural information. The following reactions were run in a rocking autoclave under pressure (145 psi of 20% O.sub.2 in N.sub.2) using sulfuric acid (0.11 gms) as the catalyst, acetic anhydride (11.4 ml) and benzylidene diacetate (4 gms) in benzene (50 ml) for the time indicated at the temperature shown in the table.  The species has no significant existence in solution but forms stable crystals. 4
C., and initial pressures at room temperature, of from about 100 to 300 psig, of an O.sub.2 -containing gas, preferably 190 to 220 psig, in an autoclave for periods ranging from about 15 minutes to 4 hours, depending upon the pressures and temperatures employed. PHCH(OAc).sub.2 Mixture Mixture ______________________________________ 1 0.5 200 99 21% 25% 2 1.0 200 99 22% 23% 3 1.0 170 78 8% 8% ______________________________________. C., preferably 200.degree. The process of claim 1 wherein the acetic anhydride is present in amounts of 2-3 times by weight of the benzylidene diacetate. Property Name Property Value Reference Molecular Weight 625.5 g/mol Computed by PubChem 2.1 (PubChem release 2019.06.18) Hydrogen Bond Donor Count 8 Computed by Cactvs 18.104.22.168 (PubChem release 2019.06.18) CC(=O)O.CC(=O)O.c1cc (ccc1NC(=N)NC(=N)NCC CCCCNC(=N)NC(=N)Nc2c cc(cc2)Cl)Cl Copy. Benzylidene diacetate may be converted to phenyl acetate and methylene diacetate by an acid-catalyzed reaction in the presence of oxygen or air, and acetic anhydride, at elevated temperatures and pressures. The 2-Benzylidene-1,3-dioxolane molecule contains a total of 22 atom(s). 15-18. to 220.degree. The chemical structure image of 2-Benzylidene-1,3-dioxolane is available in chemical structure page of 2-Benzylidene-1,3-dioxolane, which specifies the molecular geometry, i.e., the spatial arrangement of atoms in the chemical formula of 2-Benzylidene-1,3-dioxolane and the chemical bonds that hold the atoms together. CopyCopied, InChI=1S/C11H12O4/c1-8(12)14-11(15-9(2)13)10-6-4-3-5-7-10/h3-7,11H,1-2H3
Phenylmethylene diacetate Molecular Formula C 11 H 12 O 4 Average mass 208.211 Da Monoisotopic mass 208.073563 Da ChemSpider ID 21242158 Then, try SnaPeaks – simply upload your MS/MS data and SnaPeaks will provide what’s in your natural products. This invention relates to a process for the preparation of phenyl acetate and methylene diacetate. As a food additive, it has E number E262 and is used to impart a salt and vinegar flavor. It is a salt of acetic acid. The 2-Benzylidene-1,3-dioxolane compound may have different names depending on the various different situations of industrial applications. The process of claim 1 wherein the acid catalyst is present in amounts of 10.sup.-1 to 10.sup.-2 moles/liter. benzylidene diacetate [PhCH[OC(=O)CH3]2] ©2004-2020 Universal Taxonomic Services. It is a salt of acetic acid. "Crystal structures of some acid salts of monobasic acids. A, 779, 1997, 287-297. Preparation and structure. These compounds can also be oxidized to carboxylic acids in order to open important biological molecules, such as glycosaminoglycans, to other routes of synthesis. No art has been found which bears on this novel process. © 2020 ChemEssen, Inc. All rights reserved. The long-range spin–spin coupling constant over six formal bonds, 6 J, is used to derive apparent twofold barriers to rotation about the exocyclic C(1)—C bond in the two solutions.The conformation of lowest energy has the α. Heat of Vaporization at Normal Boiling Point, LogP (Octanol-Water Partition Coefficient), Ghose-Crippen Octanol-Water Partition Coefficient (logP), Moriguchi Octanol-Water Partition Coefficient (logP), Activity Score for Ion Channel Modulators, Activity Score for Nuclear Receptor Ligands, Structure Data File (SDF/MOL File) of 2-Benzylidene-1,3-dioxolane, download in the SDF page of 2-Benzylidene-1,3-dioxolane, Chemical structure of 2-Benzylidene-1,3-dioxolane, chemical structure page of 2-Benzylidene-1,3-dioxolane, Molecular weight of 2-Benzylidene-1,3-dioxolane, molecular weight page of 2-Benzylidene-1,3-dioxolane, 22 atom(s) - 10 Hydrogen atom(s), 10 Carbon atom(s) and 2 Oxygen atom(s), 23 bond(s) - 13 non-H bond(s), 7 multiple bond(s), 1 rotatable bond(s), 1 double bond(s), 6 aromatic bond(s), 1 five-membered ring(s), 1 six-membered ring(s) and 2 ether(s) (aliphatic).